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  Dithiolene Nickel

The dithiolene dyes are valuable for their thermal stability.  They absorb in the near infrared over a wide range of wavelengths depending upon the organic groups on the dithiolene ring.  Their properties of solubility and absorptivity are also tied to the organic groups on the ring carbon atoms.

Most dithiolenes are high melting solids, which have very low solubility in common organic solvents.  They show excellent compatibility in polycarbonate and other resins.  There is no evidence of bloom and they appear to be quite stable to long term heat exposure.

Dithiolenes degrade slowly in sunlight but this is similar to any organic soluble dye. Their light stability is greater than the amminium dyes of the 1000 and 2000 series.

Aliphatic derivatives, where "R" is methyl or propyl, have their peak absorption below 800nm. Aromatic substitution, where "R" is phenyl or substituted phenyl, produce dyes with absorption between 850 and 1000nm. 
 
When an electron-rich donating group such as the dialkylamino group is substituted on the aromatic ring, absorption peaks at 1050nm or higher.

Epolight™

lambda max, nm

substitution

3079

771

aliphatic

3036

773

aliphatic

3211

785

aliphatic

3030

791

aliphatic

3442

817

aliphatic & aromatic

3063

858

aromatic

3443

868

aromatic

3157

886

aromatic

3159

890

aromatic

3116

892

aromatic

3182

907

aromatic

3138

924

aromatic

3185

931

aromatic

3169

934

aromatic

3130

950

aromatic

3072

1054

aromatic

 
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Last Updated on 4/11/08